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Preliminary study of trace element emissions and control during coal combustion

ZHANG Junying, ZHAO Yongchun, DING Feng, ZENG Hancai, ZHENG Chuguang

《能源前沿（英文）》 2007年 第1卷 第3期   页码 273-279 doi: 10.1007/s11708-007-0038-2

摘要： Hazardous trace element emissions have caused serious harm to human health in China. Several typical high-toxic trace element coals were collected from different districts and were used to investigate the emission characteristics of toxic trace elements (As, Se, Cr, Hg) and to explore preliminary control methods. Coal combustion tests were conducted in several bench-scale furnaces including drop tube furnace (DTF), circulating fluidized bed (CFB) combustion furnace, and fixed-bed combustion furnace. Calcium oxide was used to control the emission of arsenic and selenium. The granular activated carbons (AC) and activated-carbon fibers (ACF) were used to remove mercury in the flue gas from coal combustion. The chemical composition and trace element contents of ash and particulate matter (PM) were determined by X-ray fluorescence (XRF) spectrometry and inductively coupled plasma-atomic emission spectrometry (ICP-AES), respectively. The speciation and concentration of mercury were investigated using the Ontario-Hydro method. X-ray diffraction spectrometry (XRD) was used to determine the mineral composition of production during combustion experiments. With the addition of a calcium-based sorbent, arsenic concentration in PM sharply decreased from 0.25–0.11 mg/m. In fixed-bed combustion of coal, the retention rates of selenium volatiles were between 11.6% and 50.7% using lime. In the circulating fluidized-bed combustion of coal, the content of selenium in ash from the chimney was reduced to one-fourth of its original value and that in leaching water from the chimney decreased by two orders of magnitude using lime. Calcium-based sorbent is an effective additive to control the emission of As and Se during coal combustion. The emission of chromium is influenced by the occurrence mode of Cr in coal. Chromium emission in PM during coal combustion is 55.5 and 34.7 μg/m for Shenbei coal and mixed Pingdingshan coal, respectively. The adsorptive capacity of granular activated carbon for Hg is significantly enhanced through ZnCl-impregnation. The activated carbon fibers showed decent efficiency in mercury adsorption, on which surface oxygen complex showed positive effects on mercury adsorption.

关键词： Pingdingshan     occurrence     plasma-atomic emission     chemical composition     Several typical    

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Re-evaluation of several heavy metals removal by natural limestones

Ali SDIRI,Samir BOUAZIZ

《化学科学与工程前沿（英文）》 2014年 第8卷 第4期   页码 418-432 doi: 10.1007/s11705-014-1455-5

摘要： Different treatment technologies have been efficiently applied to remove heavy metals from wastewater. Efforts have been made to find out the most economic water treatment technology by using low cost and easily accessible natural materials. On the other hand, heavy metals are the most threatening groundwater contaminants because of their toxicity and harmful effects on human and biota. This review discusses the use of natural geological materials for heavy metal removal in aqueous systems. Special attention has been devoted to natural limestone through a systematic inventory of relevant published reports. The removal of toxic metals may include different mechanisms (e.g., physisorption, chemisorptions, precipitation, etc.), depending on the physico-chemical properties of the material and the removed metal. Sorption of toxic metals (e.g., Pb, Cu, Cd, Zn, Cr, Hg, etc.) onto natural limestone involved precipitation of metal carbonate as a predominant removal process, but often subordinated by adsorption and ion exchange, depending on the physico-chemical properties of the studied limestone.

关键词： limestone     heavy metals     sorption     wastewater     passive treatment technology    

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生态文明建设若干战略研究

“生态文明建设若干战略问题研究”综合组

《中国工程科学》 2015年 第17卷 第8期   页码 1-7

摘要：

为实现我国从“工业文明”到“生态文明”的转变，2013年中国工程院联合国家开发银行股份有限公司和清华大学开展了“生态文明建设若干战略问题研究”重大咨询研究项目。研究从战略层面探索生态文明建设的三大支柱（资源节约、生态安全和环境保护）如何与新型工业化、城镇化、农业现代化相融合等重大战略问题。研究提出了国土生态安全与水土资源配置格局、生态文明建设中的能源可持续发展战略、生态保护和建设战略、环境保护战略、新型工业化战略、新型城镇化战略、农业现代化战略、绿色消费与文化教育战略、绿色交通运输战略；提出了“十三五”时期生态文明建设目标与重点任务以及生态文明建设政策保障，为国家加快推进生态文明建设提供决策支撑。

关键词： 生态文明建设；工程科技；战略    

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Several issues to be considered for long-term better behavior of concrete gravity dams

Jinsheng JIA,

《结构与土木工程前沿（英文）》 2010年 第4卷 第1期   页码 40-46 doi: 10.1007/s11709-010-0006-5

摘要： Along with economic, social quick development and urbanization, dams and reservoirs are of strategic importance for flood control, water supply, electricity production, irrigation, etc., both for developed countries and for developing countries. Climate change is a new challenging issue to be considered which will speed up the development of hydropower in developing countries. More and more attention will be paid on the long-term better behavior of dams to guarantee the safety of the people involved and the better development of the world. There are about 50000 old dams in the world and a lot of them have been completed and operated for more than 50 years. However, how do we evaluate the dams’ safety? How do we make the decision to do rehabilitation work or to rebuild a new dam based on evaluation results? The life span and the real safety status of old dams becomes a challenging task for the dam society, especially for China because it has more than 6000 dams to be evaluated and rehabilitated within the next few years. Based on the investigation of the Fengman gravity dam, which is 91.7 m high, operated since 1943 and suffered uplift pressure, freeze and thaw problems, etc., discussions on the life span evaluation of old concrete gravity dams have been made. The reasonable coefficient of dam safety has been discussed. The social decision for the final choice after comprehensive studies has been introduced.

关键词： dam safety     economic life span     structural life span     environmental life span     rehabilitation     social decision    

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Effect of the ultraviolet/chlorine process on microbial community structure, typical pathogens, and antibiotic

《环境科学与工程前沿（英文）》 2022年 第16卷 第8期 doi: 10.1007/s11783-022-1521-z

摘要：

• UV/chlorine can effectively remove VBNC pathogens, ARGs and MGEs in reclaimed water.

关键词： UV/chlorine process     Pathogen     Antibiotic resistance genes     High-throughput qPCR     Reclaimed water    

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Measurement and analysis of typical motion error traces from a circular test

LI Xiaoli, LIU Huanlao

《机械工程前沿（英文）》 2008年 第3卷 第2期   页码 146-150 doi: 10.1007/s11465-008-0033-2

摘要： The circular test provides a rapid and efficient way of measuring the contouring accuracy of a machine tool. To get the actual point coordinate in the work plane, an improved measurement instrument - a new ball bar test system - is presented in this paper to identify both the radial error and the rotation angle error when the machine is manipulated to move in circular traces. Based on the measured circular error, a combination of Fourier components is chosen to represent the systematic form error that fluctuates in the radial direction. The typical motion errors represented by the corresponding Fourier components can thus be identified. The values for machine compensation can be calculated and adjusted until the desired results are achieved.

关键词： machine compensation     direction     combination     desired     efficient    

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Occurrence and fate of typical antibiotics in wastewater treatment plants in Harbin, North-east China

Weihua Wang, Wanfeng Zhang, Hong Liang, Dawen Gao

《环境科学与工程前沿（英文）》 2019年 第13卷 第3期 doi: 10.1007/s11783-019-1118-3

摘要：

• The concentration distributions and removals of 12 antibiotics were investigated.

• Macrolides and fluoroquinolones presented relatively higher concentrations.

• The removal of antibiotics did not differ among the different treatment processes.

关键词： Antibiotics     WWTPs     Occurrence     Removal efficiency    

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Multimedia distribution and health risk assessment of typical organic pollutants in a retired industrial

《环境科学与工程前沿（英文）》 2023年 第17卷 第11期 doi: 10.1007/s11783-023-1742-9

摘要：

● A fine portrayal of organic pollutants in a retired industrial park is provided.

关键词： Organic pollutants     Retired industrial park     Spatial correlation     Health risk assessment    

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Understanding coupled factors that affect the modelling accuracy of typical planar compliant mechanisms

Guangbo HAO,Haiyang LI,Suzen KEMALCAN,Guimin CHEN,Jingjun YU

《机械工程前沿（英文）》 2016年 第11卷 第2期   页码 129-134 doi: 10.1007/s11465-016-0392-z

摘要：

In order to accurately model compliant mechanism utilizing plate flexures, qualitative planar stress (Young’s modulus) and planar strain (plate modulus) assumptions are not feasible. This paper investigates a quantitative equivalent modulus using nonlinear finite element analysis (FEA) to reflect coupled factors in affecting the modelling accuracy of two typical distributed-compliance mechanisms. It has been shown that all parameters have influences on the equivalent modulus with different degrees; that the presence of large load-stiffening effect makes the equivalent modulus significantly deviate from the planar assumptions in two ideal scenarios; and that a plate modulus assumption is more reasonable for a very large out-of-plane thickness if the beam length is large.

关键词： coupling factors     modelling accuracy     compliant mechanisms     equivalent modulus    

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Hexachlorobutadiene emissions from typical chemical plants

Minxiang Wang, Lili Yang, Xiaoyun Liu, Zheng Wang, Guorui Liu, Minghui Zheng

《环境科学与工程前沿（英文）》 2021年 第15卷 第4期 doi: 10.1007/s11783-020-1352-8

摘要： Abstract • Unintentional HCBD production in typical chemical plants was investigated. • The highest HCBD concentrations were found in the bottom residue. • Tri/tetrachloroethylene production processes were important HCBD sources. Hexachlorobutadiene (HCBD) was classed as a persistent organic pollutant under the Stockholm Convention in 2015. HCBD is mainly an unintentionally produced by-product of chlorinated hydrocarbon (e.g., trichloroethylene and tetrachloroethylene) synthesis. Few studies of HCBD formation during chemical production processes have been performed, so HCBD emissions from these potentially important sources are not understood. In this study, HCBD concentrations in raw materials, intermediate products, products, and bottom residues from chemical plants producing chlorobenzene, trichloroethylene, and tetrachloroethylene were determined. The results indicated that HCBD is unintentionally produced at much higher concentrations in trichloroethylene and tetrachloroethylene plants than chlorobenzene plants. The sum of the HCBD concentrations in the samples from all of the trichloroethylene and tetrachloroethylene production stages in plant PC was 247000 mg/mL, about three orders of magnitude higher than the concentrations in the tetrachloroethylene production samples (plant PB) and about six orders of magnitude higher than the concentrations in the chlorobenzene production samples (plant PA). The HCBD concentrations were highest in bottom residues from all of the plants. The concentrations in the bottom residue samples contributed 24%–99% of the total HCBD formed in the chemical production plants. The bottom residue, being hazardous waste, could be disposed of by incineration. The HCBD concentrations were much higher in intermediate products than raw materials, indicating that HCBD formed during production of the intended chemicals. The results indicate the concentrations of HCBD unintentionally produced in typical chemical plants and will be useful in developing protocols for controlling HCBD emissions to meet the Stockholm Convention requirements.

关键词： Hexachlorobutadiene     Chemical plant     Chlorobenzene     Trichloroethylene     Tetrachloroethylene    

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Structural optimization of typical rigid links in a parallel kinematic machine

Xinjun LIU, Zhidong LI, Xiang CHEN

《机械工程前沿（英文）》 2011年 第6卷 第3期   页码 344-353 doi: 10.1007/s11465-011-0227-x

摘要：

The motion dynamics and accuracy of parallel kinematic machines largely depend on the weights and rigidity of typical rigid links. Therefore, these parts should be designed in such a way that they are light but rigid. This work employs the techniques of topology and size optimization to design two typical rigid links of a parallel kinematic machine (PKM) and subsequently obtains applicable structures for them. The calculation models are established, and a new algorithm called the Guide-Weight method is introduced to solve topology optimization problems. The commercial software Ansys is used to perform size optimization.

关键词： topology optimization     size optimization     parallel kinematic machine (PKM)    

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Hydraulic properties of typical salt-affected soils in Jiangsu Province, China

CHEN Xiaomin, SHEN Qirong, XU Yangchun

《环境科学与工程前沿（英文）》 2007年 第1卷 第4期   页码 443-447 doi: 10.1007/s11783-007-0070-9

摘要： Every year about 1,500 ha of land is reclaimed from the sea along the coastline of Jiangsu Province, China. It is important to characterize the hydraulic properties of this reclaimed land to be able to predict and manage salt and wa

关键词： hydraulic     Jiangsu Province     coastline     important     reclaimed    

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Simultaneous quantification of several classes of antibiotics in water, sediments, and fish muscles by

WEI Yimei,ZHANG Yuan,XU Jian,GUO Changsheng,LI Lei,FAN Wenhong

《环境科学与工程前沿（英文）》 2014年 第8卷 第3期   页码 357-371 doi: 10.1007/s11783-013-0580-6

摘要： Precise and sensitive methods for the simultaneous determination of different classes of antibiotics, including sulphonamides, fluoroquinolones, macrolides, tetracyclines, and trimethoprim in surface water, sediments, and fish muscles were developed. In water samples, drugs were extracted with solid-phase extraction (SPE) by passing 1000 mL of water through hydrophilic lipophilic balanced (HLB) SPE cartridges. Sediment samples were solvent-extracted, followed by tandem SPE (strong anion exchange (SAX) + HLB) clean-ups. Fish muscles were extracted by a mixture of acetonitrile and citric buffer (80:20, v/v) solution, and cleaned by SPE. Liquid chromatography–tandem mass spectrometry (LC-MS/MS) with multiple reaction monitoring (MRM) detection was employed to quantify all compounds. The recoveries for the antibiotics in the spiked water, sediment, and fish samples were 60.2%–95.8%, 48.1%–105.3%, and 59.8%–103.4%, respectively. The methods were applied to samples taken from Dianchi Lake, China. It showed that concentrations of the detected antibiotics ranged from limits of quantification (LOQ) to 713.6 ng·L (ofloxacin) in surface water and from less than LOQ to 344.8 μg·kg (sulphamethoxazole) in sediments. The number of detected antibiotics and the overall antibiotic concentrations were higher in the urban area than the rural area, indicating the probable role of livestock and human activities as important sources of antibiotic contamination. In fish muscles, the concentration of norfloxacin was the highest (up to 38.5 μg·kg ), but tetracyclines and macrolides were relatively low. Results showed that the methods were rapid and sensitive, and capable of determining several classes of antibiotics from each of the water, sediment, and fish matrices in a single run.

关键词： antibiotics     liquid chromatography–tandem mass spectrometry (LC-MS/MS)     water     sediment     fish muscle    

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Partial anammox achieved in full scale biofilm process for typical domestic wastewater treatment

《环境科学与工程前沿（英文）》 2022年 第16卷 第3期 doi: 10.1007/s11783-021-1467-6

摘要：

• A full scale biofilm process was developed for typical domestic wastewater treatment.

关键词： Full scale     Anammox     Domestic wastewater     Biofilm     Candidatus Brocadia    

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Resource utilization of typical biomass wastes as biochars in removing plasticizer diethyl phthalate

《环境科学与工程前沿（英文）》 2023年 第17卷 第1期 doi: 10.1007/s11783-023-1605-4

摘要：

● Six largely produced agricultural biomass wastes were pyrolyzed into biochars.

关键词： Plastic pollution     Phthalic acid esters     Designed biochar     Wetland plant     Adsorption    

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标题 作者 时间 类型 操作

Preliminary study of trace element emissions and control during coal combustion

ZHANG Junying, ZHAO Yongchun, DING Feng, ZENG Hancai, ZHENG Chuguang

期刊论文

Re-evaluation of several heavy metals removal by natural limestones

Ali SDIRI,Samir BOUAZIZ

期刊论文

生态文明建设若干战略研究

“生态文明建设若干战略问题研究”综合组

期刊论文

Several issues to be considered for long-term better behavior of concrete gravity dams

Jinsheng JIA,

期刊论文

Effect of the ultraviolet/chlorine process on microbial community structure, typical pathogens, and antibiotic

期刊论文

Measurement and analysis of typical motion error traces from a circular test

LI Xiaoli, LIU Huanlao

期刊论文

Occurrence and fate of typical antibiotics in wastewater treatment plants in Harbin, North-east China

Weihua Wang, Wanfeng Zhang, Hong Liang, Dawen Gao

期刊论文

Multimedia distribution and health risk assessment of typical organic pollutants in a retired industrial

期刊论文

Understanding coupled factors that affect the modelling accuracy of typical planar compliant mechanisms

Guangbo HAO,Haiyang LI,Suzen KEMALCAN,Guimin CHEN,Jingjun YU

期刊论文

Hexachlorobutadiene emissions from typical chemical plants

Minxiang Wang, Lili Yang, Xiaoyun Liu, Zheng Wang, Guorui Liu, Minghui Zheng

期刊论文

Structural optimization of typical rigid links in a parallel kinematic machine

Xinjun LIU, Zhidong LI, Xiang CHEN

期刊论文

Hydraulic properties of typical salt-affected soils in Jiangsu Province, China

CHEN Xiaomin, SHEN Qirong, XU Yangchun

期刊论文

Simultaneous quantification of several classes of antibiotics in water, sediments, and fish muscles by

WEI Yimei,ZHANG Yuan,XU Jian,GUO Changsheng,LI Lei,FAN Wenhong

期刊论文

Partial anammox achieved in full scale biofilm process for typical domestic wastewater treatment

期刊论文

Resource utilization of typical biomass wastes as biochars in removing plasticizer diethyl phthalate

期刊论文